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Zeroeth Law of Thermodynamics

Let's just state the zeroeth Law of Thermodynamics

If bodies \bgroup\color{blue}$ A$\egroup and \bgroup\color{blue}$ B$\egroup are in thermal but not mechanical contact and heat flows from \bgroup\color{blue}$ A$\egroup to \bgroup\color{blue}$ B$\egroup and if \bgroup\color{blue}$ B$\egroup is in thermal contact with \bgroup\color{blue}$ C$\egroup and heat flows from \bgroup\color{blue}$ B$\egroup to \bgroup\color{blue}$ C$\egroup then

Heat will flow from \bgroup\color{blue}$ A$\egroup to \bgroup\color{blue}$ C$\egroup if they are in thermal contact. In other words,

$\displaystyle \input{equations/zero-law-1}$ (03-3)

$\displaystyle \input{equations/zero-law-2}$ (03-4)

We can call the body \bgroup\color{blue}$ B$\egroup a thermometer and use the zeroeth law.3

The temperature can be related to \bgroup\color{blue}$ \Theta$\egroup, we can just call \bgroup\color{blue}$ T=\Theta$\egroup. This can be done rigorously and it defines an absolute zero ( \bgroup\color{blue}$ T=0$\egroup) but let's not do this and move on.

Later we may use the entropy, \bgroup\color{blue}$ S$\egroup and internal energy, \bgroup\color{blue}$ U$\egroup, of a body to define the temperature.4

$\displaystyle \input{equations/Tdef}$ (03-5)

For a body that does no work, or has no work performed on it, the temperature is the rate at which internal energy changes with entropy.

$\displaystyle \input{equations/Tdef-alt}$ (03-6)

\bgroup\color{blue}$ U$\egroup tends to increase with \bgroup\color{blue}$ S$\egroup.

In this lecture, we have discussed state variable that gives us information about a body, an efficient way.

\begin{center}\vbox{\input{tables/int-ext}
}\end{center}

All of these quantities rely on measurement but are assumed to be independent of the type of measurement.


next up previous
Next: About this document ... Up: Lecture_03_web Previous: Intensive and Extensive Variables
W. Craig Carter 2002-09-06