- ...
1
- A functional is a function of a function;
in this case, it takes a function and maps it to a scalar
which is numerically equal to the total free energy of the system
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- ...
values2
- If represents a conserved quantity like , then
the variation must not contribute to the total content of the
system (
), but we will satisfy this requirement
automatically below.
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- ....3
-
This is one particular choice for the functional gradient,
for which there
are an infinite number of choices.
This particular choice (the gradient in the -norm
of functions) describes the physics of the problem.
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- ....4
-
For the general functional,
,
the variational derivative of is
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- ... quantity.5
-
An extensive quantity is one which depend on the total size of a system,
like the volume, enthalpy, or free energy.
A molar extensive quantity is scaled by diving by the total number of
moles in the system:
.
A molal extensive quantity is scaled by dividing by the number of
moles of a particular species.
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