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Addition of a Soluble Species

Consider the addition of a soluble species into the liquid phase (and suppose it is not very soluble at all in the solid phase) then

Question: Will the Gibbs free energy of the liquid phase increase or decrease as it dissolves a soluble species?


This is illustrated in the following figure:

Figure 27-1: Illustration of the freezing point depression when the molar Gibbs free energy of the high temperature phase is reduced.
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{\epsfig{file=figures/T-depress.eps}}
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Thus we see that a soluble species in the liquid leads to ``freezing point depression.'' This is the reason that roads get salted when they get icy--and the reason that old-timers used to add salt to ice-water when making ice cream.


W. Craig Carter 2002-11-22