Consider the addition of a soluble species into the liquid phase (and suppose it is not very soluble at all in the solid phase) then
Question: Will the Gibbs free energy of the liquid phase increase or decrease as it dissolves a soluble species?
This is illustrated in the following figure:
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Thus we see that a soluble species in the
liquid leads to ``freezing point
depression.''
This is the reason that roads get salted when
they get icy--and the reason that old-timers
used to add salt to ice-water when
making ice cream.