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The behavior of G during a phase change.

Consider how the molar Gibbs energy changes when ice melts:

Figure 15-3: Plot of molar free energy of solid and liquid phases against temperature. The curve with the lowest value of $ G$ indicates which phase is most stable at that particular temperature.
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Figure 15-4: Plot of phase fractions of the molar free energy of solid and liquid phases against enthalpy. The molar Gibb's free energy of each phase is equal during the transformation regardless of how much material is present.
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W. Craig Carter 2002-10-08