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Binary Phase Diagrams

There is a graphical construction that allows you to determine the chemical potentials of chemical species in solution:

Figure 2-4: A graphical construction of great importance.
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This construction and the equality of chemical potentials results in the common tangent construction between several phases of heterogeneous solution in a binary alloy:


Figure 2-5: Common Tangent Construction
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Which allows the construction of binary phase diagrams, for example:

Figure 2-6: Eutectic binary phase diagram
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The two phase regions are composed of the limiting compositions on either side of the two-phase region on the phase diagram; the lever rule allows us to determine the fractions of each phase.

There are four main types of binary phase diagrams: Eutectic-type, Peritectic-type, Spinodal, and Lens. You should be able to draw these without too much effort.



next up previous
Next: Multicomponent Phase Diagrams Up: Continuum Thermodynamics Previous: Solution Thermodynamics
W. Craig Carter 2002-09-05