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Some work always gets wasted as heat.
In other words, all of the work that is done on a body
cannot get stored as internal energy--some of it leaks out as heat.
The amount of wasted work is minimized when
a process is carried out reversibly. A reversible process happens very slowly and
the system is always in equilibrium (i.e., the intensive variables are uniform)
during a reversible process.
This idea of a minimum of something is very useful because it allows the definition
of new thermodynamic variables associated with the limiting (minimizing) case.
This is an abstraction--like the notion of limits in calculus--which seems confusing
at first, but becomes natural with familiarity.
W. Craig Carter
2002-09-05